Surface Functionalized SAPO-34 for Mixed Matrix Membranes in CO₂/CH₄ and CO₂/N₂ Separations

Hybrid and Mixed Matrix Membranes for Separations from Fermentations

Fermentations provide an alternative to fossil fuels for accessing a number of biofuel and chemical products from a variety of renewable and waste substrates. The recovery of these dilute fermentation products from the broth, however, can be incredibly energy intensive as a distillation process is generally involved and creates a barrier to commercialization. Membrane processes can provide a lo...

Purified and Functionalized MWCNTs: Application In CO2/CH4 Separation Using Mixed Matrix Membranes

   To fabricate a defect free and high performance mixed matrix membrane (MMM), one approach is the functionalization of inorganic nanofillers (as dispersed phase) in the organic polymer matrix (as continuous phase) to modify the interactions between two phases.  For this purpose,, raw multi-walled carbon nanotubes (rMWCNTs) were purified by acid mixture (HNO3/H2SO<sub...

Advanced Mixed Matrix Membranes for Biofuel Related Separations

Metal organic framework mixed matrix membranes for gas separations

Please cite this article in press as: R. Adams et Mixed matrix membranes (MMMs) for gas separations are traditionally comprised of zeolites dispersed in a polymer matrix in order to improve desired penetrant permeability and selectivity. Zeolites have a variety of drawbacks for this application – chiefly, a limited number of possible zeolite structures – that limit their potential for use in MM...

Cation-exchanged SAPO-34 for adsorption-based hydrocarbon separations: predictions from dispersion-corrected DFT calculations.

The influence of the nature of the cation on the interaction of the silicoaluminophosphate SAPO-34 with small hydrocarbons (ethane, ethylene, acetylene, propane, propylene) is investigated using periodic density-functional theory calculations including a semi-empirical dispersion correction (DFT-D). Initial calculations are used to evaluate which of the guest-accessible cation sites in the chab...